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Kinetic and mechanistic investigations of hydrothermal transformations in zinc phosphates.

Abstract:

The room-temperature crystallization of [C(6)N(2)H(18)][Zn(HPO(4))(H(2)PO(4))(2)], an organically templated zinc phosphate containing [Zn(2)(HPO(4))(2)(H(2)PO(4))(4)](4)(-) molecular anions, and its transformation to compounds containing either one- or two-dimensional inorganic components, [C(6)N(2)H(18)][Zn(3)(H(2)O)(4)(HPO(4))(4)], [C(4)N(2)H(12)][Zn(HPO(4))(2)(H(2)O)], or [C(3)N(2)H(6)][Zn(4)(OH)(PO(4))(3)], under hydrothermal conditions were studied in-situ using energy-dispersive X-ray d...

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Publication status:
Published

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Publisher copy:
10.1021/ja049860w

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
Journal of the American Chemical Society
Volume:
126
Issue:
21
Pages:
6673-6679
Publication date:
2004-06-01
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
Language:
English
Pubs id:
pubs:51180
UUID:
uuid:1b8f7af1-8260-4b69-887a-34425db8855c
Local pid:
pubs:51180
Source identifiers:
51180
Deposit date:
2012-12-19

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