Journal article
Correction factors for the analysis of voltammetric peak currents measured using staircase voltammetry
- Abstract:
-
The use of staircase voltammetry for the measurement of reversible diffusional redox species under a linear mass-transport regime leads to significant suppression of the peak currents (up to 20% for larger step sizes) and an increase in the peak-to-peak separation (cf. ∆ Epp ~ 70 mV at the reversible limit as opposed to 57 mV). These discrepancies between the voltammetric results of a staircase and true analogue voltammogram may lead to mis-interpretation of data. This work provides an overvi...
Expand abstract
- Publication status:
- Published
- Peer review status:
- Peer reviewed
Actions
Access Document
- Files:
-
-
(Accepted manuscript, pdf, 764.0KB)
-
- Publisher copy:
- 10.1016/j.jelechem.2015.10.004
Why is the content I wish to access not available via ORA?
Bibliographic data (the information relating to research outputs) and full-text items (e.g. articles, theses, reports, etc.) arrive in ORA from several different sources. Unfortunately we are not able to make available the full-text for every research output.
Please contact the ORA team (
) if you have queries regarding unavailable content OR if you are aware of a full-text copy we can make available.
) if you have queries regarding unavailable content OR if you are aware of a full-text copy we can make available.
Content may be unavailable for the following four reasons
-
Version unsuitable
-
We have not obtained a suitable full-text for a given research output. See this page for more information.
-
Recently completed
-
Sometimes content is held in ORA but is unavailable for a fixed period of time to comply with the policies and wishes of rights holders.
-
Permissions
-
All content made available in ORA should comply with relevant rights, such as copyright. See this page for more information.
-
Clearance
-
Some thesis volumes scanned as part of the digitisation scheme funded by Dr Leonard Polonsky are currently unavailable due to sensitive material or uncleared third-party copyright content. We are attempting to contact authors whose theses are affected.
Alternative access to the full-text
You may be able to access the full-text directly from the publisher's website using the 'Publisher Copy' link in the 'Links & Downloads' box from a research output's ORA record page. This method may require an institutional or individual subscription to the journal/resource.
Authors
Funding
Bibliographic Details
- Publisher:
- Elsevier Publisher's website
- Journal:
- Journal of Electroanalytical Chemistry Journal website
- Volume:
- 758
- Pages:
- 1-6
- Publication date:
- 2015-10-18
- Acceptance date:
- 2015-10-05
- DOI:
- ISSN:
-
1572-6657
- Source identifiers:
-
572881
Item Description
- Keywords:
- Pubs id:
-
pubs:572881
- UUID:
-
uuid:1ab8a1b4-6400-45cc-96e9-e73742c46ba8
- Local pid:
- pubs:572881
- Deposit date:
- 2016-04-25
Terms of use
- Copyright holder:
- Elsevier BV
- Copyright date:
- 2015
- Notes:
- Copyright © 2015 Elsevier B.V. This is the accepted manuscript version of the article. The final version is available online from Elsevier at: https://doi.org/10.1016/j.jelechem.2015.10.004
If you are the owner of this record, you can report an update to it here: Report update to this record