- Abstract:
-
The use of staircase voltammetry for the measurement of reversible diffusional redox species under a linear mass-transport regime leads to significant suppression of the peak currents (up to 20% for larger step sizes) and an increase in the peak-to-peak separation (cf. ∆ Epp ~ 70 mV at the reversible limit as opposed to 57 mV). These discrepancies between the voltammetric results of a staircase and true analogue voltammogram may lead to mis-interpretation of data. This work provides an overvi...
Expand abstract - Publication status:
- Published
- Peer review status:
- Peer reviewed
- Version:
- Accepted Manuscript
- Files:
-
-
(pdf, 764.0KB)
-
- Publisher copy:
- 10.1016/j.jelechem.2015.10.004
-
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- Publisher:
- Elsevier Publisher's website
- Journal:
- Journal of Electroanalytical Chemistry Journal website
- Volume:
- 758
- Pages:
- 1-6
- Publication date:
- 2015-10-18
- Acceptance date:
- 2015-10-05
- DOI:
- ISSN:
-
1572-6657
- URN:
-
uuid:1ab8a1b4-6400-45cc-96e9-e73742c46ba8
- Source identifiers:
-
572881
- Local pid:
- pubs:572881
- Copyright holder:
- Elsevier B.V.
- Copyright date:
- 2015
- Notes:
-
Copyright © 2015 Elsevier B.V. This is the accepted manuscript version of the article. The final version is available online from Elsevier at: https://doi.org/10.1016/j.jelechem.2015.10.004
Journal article
Correction factors for the analysis of voltammetric peak currents measured using staircase voltammetry
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