Journal article icon

Journal article

Correction factors for the analysis of voltammetric peak currents measured using staircase voltammetry

Abstract:

The use of staircase voltammetry for the measurement of reversible diffusional redox species under a linear mass-transport regime leads to significant suppression of the peak currents (up to 20% for larger step sizes) and an increase in the peak-to-peak separation (cf. ∆ Epp ~ 70 mV at the reversible limit as opposed to 57 mV). These discrepancies between the voltammetric results of a staircase and true analogue voltammogram may lead to mis-interpretation of data. This work provides an overvi...

Expand abstract
Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted Manuscript

Actions


Access Document


Files:
Publisher copy:
10.1016/j.jelechem.2015.10.004

Authors


More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
Publisher:
Elsevier Publisher's website
Journal:
Journal of Electroanalytical Chemistry Journal website
Volume:
758
Pages:
1-6
Publication date:
2015-10-18
Acceptance date:
2015-10-05
DOI:
ISSN:
1572-6657
URN:
uuid:1ab8a1b4-6400-45cc-96e9-e73742c46ba8
Source identifiers:
572881
Local pid:
pubs:572881

Terms of use


Metrics


Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP