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Open-circuit voltage and effective gap of organic solar cells

Abstract:

The open-circuit voltage (VOC) of an organic solar cell is limited by the donor-acceptor material system. The effective gap E g eff between the electron affinity of the acceptor and the ionization potential of the donor is usually regarded as the upper limit for VOC, which is only reached for T → 0 K. This relation is confirmed for a number of small-molecule bulk heterojunction p-i-n type solar cells by varying the temperature and illumination intensity. With high precision, the low temperatu...

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Publisher copy:
10.1002/adfm.201301048

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Institution:
University of Oxford
Division:
MPLS
Department:
Physics
Sub department:
Condensed Matter Physics
Role:
Author
Journal:
Advanced Functional Materials
Volume:
23
Issue:
46
Pages:
5814-5821
Publication date:
2013-12-10
DOI:
EISSN:
1616-3028
ISSN:
1616-301X
Pubs id:
pubs:445392
UUID:
uuid:1aa4cc44-9117-42a1-a191-f960f497c9cc
Local pid:
pubs:445392
Source identifiers:
445392
Deposit date:
2014-01-27

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