Journal article icon

Journal article

Colorimetric fluoride ion sensing by polyborylated ferrocenes: structural influences on thermodynamics and kinetics.

Abstract:

The thermodynamic factors underlying the use of ferroceneboronic esters as electrochemical or colorimetric fluoride ion sensors have been investigated through the synthesis of a range of systematically related derivatives differing in the number/nature of the boronic ester substituents and in the nature of ancillary ligands. Thus, if the shift in electrochemical potential associated with the conversion of one (or more) boronic ester group(s) to anionic boronate(s) on fluoride binding is suffi...

Expand abstract
Publication status:
Published

Actions


Access Document


Publisher copy:
10.1021/ic701494p

Authors


Bresner, C More by this author
Coombs, ND More by this author
Fallis, IA More by this author
Expand authors...
Journal:
Inorganic chemistry
Volume:
47
Issue:
3
Pages:
793-804
Publication date:
2008-02-05
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
URN:
uuid:1a7febbe-e40f-4ce8-8780-119d94940189
Source identifiers:
34001
Local pid:
pubs:34001

Terms of use


Metrics



If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP