- Abstract:
- By combining the results of both x-ray diffraction and neutron total-scattering experiments, we show that Ni (CN) 2 exhibits long-range structural order only in two dimensions, with no true periodicity perpendicular to its gridlike layers. Reverse Monte Carlo analysis gives an experimental distinction between M-C and M-N bond lengths in a homometallic cyanide framework and identifies the vibrational modes responsible for anomalous positive and negative thermal expansion in the title compound. © 2009 The American Physical Society.
- Publication status:
- Published
- Publisher copy:
- 10.1103/PhysRevB.80.054101
-
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- Journal:
- PHYSICAL REVIEW B
- Volume:
- 80
- Issue:
- 5
- Publication date:
- 2009-08-05
- DOI:
- EISSN:
-
1550-235X
- ISSN:
-
1098-0121
- URN:
-
uuid:1a62e65d-5901-4daa-8bd4-dde967f20e8a
- Source identifiers:
-
50638
- Local pid:
- pubs:50638
- Copyright date:
- 2009
Journal article
Aperiodicity, structure, and dynamics in Ni(CN)(2)
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