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Journal article

Aperiodicity, structure, and dynamics in Ni(CN)(2)

Abstract:
By combining the results of both x-ray diffraction and neutron total-scattering experiments, we show that Ni (CN) 2 exhibits long-range structural order only in two dimensions, with no true periodicity perpendicular to its gridlike layers. Reverse Monte Carlo analysis gives an experimental distinction between M-C and M-N bond lengths in a homometallic cyanide framework and identifies the vibrational modes responsible for anomalous positive and negative thermal expansion in the title compound. © 2009 The American Physical Society.
Publication status:
Published

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Publisher copy:
10.1103/PhysRevB.80.054101

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Journal:
PHYSICAL REVIEW B
Volume:
80
Issue:
5
Publication date:
2009-08-05
DOI:
EISSN:
1550-235X
ISSN:
1098-0121
URN:
uuid:1a62e65d-5901-4daa-8bd4-dde967f20e8a
Source identifiers:
50638
Local pid:
pubs:50638

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