Journal article
The influence of reaction-induced thermal convection on the electrical currents measured in chronoamperometry and cyclic voltammetry
- Abstract:
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Electrochemical reactions invariably occur with a change in the molar volume between reactant and product, as well as a change in enthalpy. These factors give rise to convective flows driven respectively by concentration and temperature and affect the mass transport in the system, but the latter has received very little attention in the scientific literature. The present study attempts to fill this gap by quantifying the effect of thermal convection on the electrical currents in chronoamperom...
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- Publication status:
- Published
- Peer review status:
- Peer reviewed
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(Accepted manuscript, pdf, 5.9MB)
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- Publisher copy:
- 10.1021/acs.jpcc.6b03413
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Authors
Funding
Clarendon Fund
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+ European Research Council
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Grant:
FP/2007-2013) / ERC Grant Agreement n. [320403
Trinity College, Oxford
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Bibliographic Details
- Publisher:
- American Chemical Society Publisher's website
- Journal:
- Journal of Physical Chemistry C Journal website
- Volume:
- 120
- Issue:
- 25
- Pages:
- 13549–13562
- Publication date:
- 2016-05-31
- Acceptance date:
- 2016-05-31
- DOI:
- EISSN:
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1932-7455
- ISSN:
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1932-7447
- Source identifiers:
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625196
Item Description
- Pubs id:
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pubs:625196
- UUID:
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uuid:19fc304b-612e-41c2-a2b6-8e45cc1055cf
- Local pid:
- pubs:625196
- Deposit date:
- 2016-06-03
Terms of use
- Copyright holder:
- American Chemical Society
- Copyright date:
- 2016
- Notes:
-
Copyright © 2016 American Chemical Society.
This is the accepted manuscript version of the article. The final version is available online from ACS at: [10.1021/acs.jpcc.6b03413]
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