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The influence of reaction-induced thermal convection on the electrical currents measured in chronoamperometry and cyclic voltammetry

Abstract:

Electrochemical reactions invariably occur with a change in the molar volume between reactant and product, as well as a change in enthalpy. These factors give rise to convective flows driven respectively by concentration and temperature and affect the mass transport in the system, but the latter has received very little attention in the scientific literature. The present study attempts to fill this gap by quantifying the effect of thermal convection on the electrical currents in chronoamperom...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted manuscript

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Publisher copy:
10.1021/acs.jpcc.6b03413

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
Clarendon Fund More from this funder
Trinity College, Oxford More from this funder
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Grant:
(FP/2007-2013) / ERC Grant Agreement n. [320403]
Publisher:
American Chemical Society Publisher's website
Journal:
Journal of Physical Chemistry C Journal website
Volume:
120
Issue:
25
Pages:
13549–13562
Publication date:
2016-05-31
DOI:
EISSN:
1932-7455
ISSN:
1932-7447
URN:
uuid:19fc304b-612e-41c2-a2b6-8e45cc1055cf
Source identifiers:
625196
Local pid:
pubs:625196
Paper number:
25

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