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Formate as a surface probe for ruthenium nanoparticles in solution 13C NMR spectroscopy.

Abstract:
Formic acid adsorption on ruthenium nanoparticles of different sizes allows differentiation of differently bound formate species by solution (13)C NMR spectroscopy (see picture). The chemical shifts are comparable to those of organometallic analogues, thus indicating that formate can act as a probe to distinguish surface features of metallic nanoparticles in solution with good quantification and resolution.
Publication status:
Published

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Publisher copy:
10.1002/anie.200805240

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Journal:
Angewandte Chemie (International ed. in English) More from this journal
Volume:
48
Issue:
8
Pages:
1443-1446
Publication date:
2009-01-01
DOI:
EISSN:
1521-3773
ISSN:
1433-7851


Language:
English
Keywords:
Pubs id:
pubs:51512
UUID:
uuid:19af57bb-5913-4c5c-8a73-b76b91fe404a
Local pid:
pubs:51512
Source identifiers:
51512
Deposit date:
2012-12-19

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