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Anion binding by multidentate Lewis acids: a DFT study

Abstract:
Density functional studies of model tribora-macrocyclic Lewis acids indicate extremely strong binding of the methyl anion, which in some cases exceeds that of B(C 6F 5) 3. In addition anion selectivity for the fluoride ion is implied by binding energies ca. 200 kJ mol -1 greater than those of other halides.
Publication status:
Published

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Publisher copy:
10.1039/b007544m

Authors


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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Fallis, IA More by this author
Howard, ST More by this author
Journal:
CHEMICAL COMMUNICATIONS
Issue:
03
Pages:
231-232
Publication date:
2001
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
URN:
uuid:199c3c93-aa92-45e1-aed1-23cd06b9480c
Source identifiers:
46071
Local pid:
pubs:46071
Language:
English

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