Journal article
Exploring photoreactions between polyazaaromatic Ru(II) complexes and biomolecules by chemically induced dynamic nuclear polarization measurements.
- Abstract:
-
Steady-state (1)H photo-chemically induced dynamic nuclear polarization (CIDNP) experiments were conducted at 14.1 T on deoxygenated (buffered pH 7) aqueous solutions of [Ru(phen)(3)](2+), [Ru(tap)(2)(phen)](2+), and [Ru(tap)(3)](2+) (tap = 1,4,5,8-tetraazaphenanthrene; phen = 1,10-phenanthroline) in the presence of guanosine-5'-monophosphate or N-acetyltyrosine. For the first time, CIDNP arising from photo-oxidation by polyazaaromatic Ru(II) complexes is reported. In agreement with the occur...
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- Publication status:
- Published
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- Publisher copy:
- 10.1021/ja9024287
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Authors
Bibliographic Details
- Journal:
- Journal of the American Chemical Society
- Volume:
- 131
- Issue:
- 34
- Pages:
- 12458-12465
- Publication date:
- 2009-09-01
- DOI:
- EISSN:
-
1520-5126
- ISSN:
-
0002-7863
- Source identifiers:
-
34825
Item Description
- Language:
- English
- Keywords:
- Pubs id:
-
pubs:34825
- UUID:
-
uuid:18327c5f-196a-4ca9-9389-8fa113508ab6
- Local pid:
- pubs:34825
- Deposit date:
- 2012-12-19
Terms of use
- Copyright date:
- 2009
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