Steady-state (1)H photo-chemically induced dynamic nuclear polarization (CIDNP) experiments were conducted at 14.1 T on deoxygenated (buffered pH 7) aqueous solutions of [Ru(phen)(3)](2+), [Ru(tap)(2)(phen)](2+), and [Ru(tap)(3)](2+) (tap = 1,4,5,8-tetraazaphenanthrene; phen = 1,10-phenanthroline) in the presence of guanosine-5'-monophosphate or N-acetyltyrosine. For the first time, CIDNP arising from photo-oxidation by polyazaaromatic Ru(II) complexes is reported. In agreement with the occur...Expand abstract
- Publication status:
- Publisher copy:
- Copyright date:
Exploring photoreactions between polyazaaromatic Ru(II) complexes and biomolecules by chemically induced dynamic nuclear polarization measurements.
Views and Downloads
If you are the owner of this record, you can report an update to it here: Report update to this record