- Abstract:
-
Manganese complexes bearing the chelating phosphaneborane ligand H 3B·dppm [dppm = bis(diphenylphosphanyl)-methane] have been prepared. Addition of H3B·dppm to Mn(CO)5Br using Na[BArF4] as a halide-abstracting reagent affords [Mn(CO)3(η2-H3B·dppm)][BAr F4] (1). This reacts with CO to open the bidentate borane to afford [Mn(CO)4(η1-H3B·dppm)] [BArF4] (2) in which the borane is now bound in a monodentate manner. The CO addition is reversible, and placing 2 under vacuum (hours) regenerates 1 qua...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1002/ejic.200600526
-
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- Journal:
- EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
- Volume:
- 2006
- Issue:
- 20
- Pages:
- 4068-4073
- Publication date:
- 2006-10-16
- DOI:
- EISSN:
-
1099-0682
- ISSN:
-
1434-1948
- URN:
-
uuid:17d85e0e-712c-447f-8819-6c1109e9e3bd
- Source identifiers:
-
51702
- Local pid:
- pubs:51702
- Language:
- English
- Keywords:
- Copyright date:
- 2006
Journal article
Chelating phosphane-boranes as hemilabile ligands - Synthesis of [Mn(CO)3(eta(2)-H3B center dot dppm)][BAr4F] and [Mn(CO)(4)(eta(1)-H3B center dot dppm)][BAr4F]
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