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Adsorption of bismuth ions on graphite chemically modified with gallic acid.

Abstract:
Graphite modified with gallic acid to form 'gallic acid-carbon' is demonstrated to be efficient for the removal of bismuth(III) ions from aqueous solutions. The uptake is demonstrated to be rapid but not to follow standard adsorption isotherm models. Instead, the uptake was found to be further promoted by the presence of the adsorbed metal. Additionally, the bismuth uptake showed linear dependence on the square of its concentration suggesting the possible formation of polymeric bismuth species. The gallic acid-carbon shows great promise as a relatively inexpensive material for solid-phase extraction and water purification with extraction efficiency close to 98%.
Publication status:
Published

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Publisher copy:
10.1039/c2cp41030c

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author


Journal:
Physical chemistry chemical physics : PCCP More from this journal
Volume:
14
Issue:
28
Pages:
10027-10031
Publication date:
2012-07-01
DOI:
EISSN:
1463-9084
ISSN:
1463-9076


Language:
English
UUID:
uuid:1737ec4f-9d94-4751-bd05-94996759ea54
Local pid:
pubs:339832
Source identifiers:
339832
Deposit date:
2012-12-19

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