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ECE and DISP processes at channel electrodes: Analytical theory

Abstract:
Analytical theory is developed for ECE and DISP1 reactions occurring at channel electrodes. Simple expressions are presented which allow the ready mechanistic interpretation of experimental data and the deduction of corresponding rate constants. These are shown to be in excellent agreement with numerical simulations and with experiments conducted on the reductions of o-bromonitrobenzene in dimethylformamide solution and of p-bromonitrobenzene in acetonitrile in the presence of light of wavelength 325 nm. © 1996 American Chemical Society.
Publication status:
Published

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Publisher copy:
10.1021/jp960975z

Authors

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author


Journal:
JOURNAL OF PHYSICAL CHEMISTRY More from this journal
Volume:
100
Issue:
33
Pages:
14130-14136
Publication date:
1996-08-15
DOI:
EISSN:
1541-5740
ISSN:
0022-3654


Language:
English
Pubs id:
pubs:45336
UUID:
uuid:17064c2a-541f-40e2-ad76-cb4ba0a2ad1a
Local pid:
pubs:45336
Source identifiers:
45336
Deposit date:
2012-12-19
ARK identifier:

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