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Selecting Room-Temperature Ionic Liquids to Optimize Voltammetric Responses: The Oxidation of NADH

Abstract:

The electrochemistry of nicotinamide adenine dinucleotide (NADH) in its reduced form was examined in two room-temperature ionic liquids (RTILs): 1-ethyl-3-methylimidazolium bis-(trifluoromethylsulfonyl)imide ([C2 mim] [NTf2]) and 1-butyl-3-methylimidazolium hexafluorophos-phate ([C4 mim] [PF6]). NADH oxidation has previously been studied in aqueous solution where it follows the pathway: one-electron oxidation to the NADH+ radical cation, deprotonation to produce the neutral NAD radical, then ...

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Publication status:
Published

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Publisher copy:
10.1149/1.3295708

Authors


O'Mahony, AM More by this author
Hardacre, C More by this author
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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Journal:
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
Volume:
157
Issue:
4
Pages:
F49-F53
Publication date:
2010
DOI:
ISSN:
0013-4651
URN:
uuid:16e71f82-1fd3-4636-9d2d-32a70e6f0ed8
Source identifiers:
51989
Local pid:
pubs:51989

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