Journal article

Formation of second-stage intermediates in anion-exchange intercalation reactions of the layered double hydroxide [LiAl2(OH)(6)]Cl center dot H2O as observed by time-resolved, in situ X-ray diffraction

Abstract:: Time-resolved in situ energy-dispersive X-ray diffraction studies on the intercalation of dicarboxylate anions (Na2C4H4O4, Na2C6H8O4, Na2-trans-C4H2O4, Na2-cis-C4H2O4, Na2-L-C4H4O5, Na2-1,2-C8H4O4, Na2-1,4-C8H4O4) into [LiAl2(OH)6]Cl·H2O have revealed the rapid formation of a second-stage intermediate phase that subsequently transforms into a phase-pure fully ion-exchanged product. These intermediates can be isolated as pure crystalline phases by reaction of the host lattice with stoichoimetric amounts of the dicarboxylate anions.

Publication status:: Published

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APA Style

Fogg, A., Dunn, J., & O'Hare, D. (1998). Formation of second-stage intermediates in anion-exchange intercalation reactions of the layered double hydroxide [LiAl2(OH)(6)]Cl center dot H2O as observed by time-resolved, in situ X-ray diffraction. CHEMISTRY OF MATERIALS, 10(1), 356–360.

MLA Style

Fogg, A, et al. “Formation of Second-Stage Intermediates in Anion-Exchange Intercalation Reactions of the Layered Double Hydroxide [LiAl2(OH)(6)]Cl Center Dot H2O as Observed by Time-Resolved, in Situ X-Ray Diffraction.” CHEMISTRY OF MATERIALS, vol. 10, no. 1, 1998, pp. 356–60.

Chicago Style

Fogg, A, J Dunn, and D O'Hare. 1998. “Formation of Second-Stage Intermediates in Anion-Exchange Intercalation Reactions of the Layered Double Hydroxide [LiAl2(OH)(6)]Cl Center Dot H2O as Observed by Time-Resolved, in Situ X-Ray Diffraction.” CHEMISTRY OF MATERIALS 10 (1): 356–60.
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Publisher copy:: 10.1021/cm970553h

Authors

+ Fogg, A More by this author

Role:: Author

+ Dunn, J More by this author

Role:: Author

+ O'Hare, D More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

Journal:: CHEMISTRY OF MATERIALS More from this journal
Volume:: 10
Issue:: 1
Pages:: 356-360
Publication date:: 1998-01-01
DOI:: 10.1021/cm970553h
EISSN:: 1520-5002
ISSN:: 0897-4756

Language:: English
Pubs id:: pubs:51156
UUID:: uuid:16a5165b-d7a6-4eaf-9c1f-eaa869ae2c4f
Local pid:: pubs:51156
Source identifiers:: 51156
Deposit date:: 2012-12-19
ARK identifier:: ark:/29072/ora_16a5165bd7a64eaf9c1feaa869ae2c4f

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Copyright date:: 1998

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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