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Palladium(0)-catalyzed arylative dearomatization of phenols.

Abstract:
The palladium-catalyzed arylative dearomatization of phenols to yield spirocyclohexadienone products in good to excellent yields has been developed. Preliminary results demonstrate that the formation of the spirocyclic all-carbon quaternary center can be accomplished with high levels of enantiocontrol (up to 91% ee).
Publication status:
Published

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Publisher copy:
10.1021/ja203644q

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Journal:
Journal of the American Chemical Society More from this journal
Volume:
133
Issue:
24
Pages:
9282-9285
Publication date:
2011-06-01
DOI:
EISSN:
1520-5126
ISSN:
0002-7863


Language:
English
Keywords:
Pubs id:
pubs:416026
UUID:
uuid:1695e7c4-21c2-47f2-8829-c8c918d8a6dd
Local pid:
pubs:416026
Source identifiers:
416026
Deposit date:
2013-11-16
ARK identifier:

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