Journal article

A second-generation catalyst for intermolecular hydroacylation of alkenes and alkynes using beta-S-substituted aldehydes: the role of a hemilabile P-O-P ligand.

Abstract:: (Chemical Equation Presented) Top of the P-O-Ps: Stabilization of a cationic rhodium catalyst with the hemilabile P-O-P ligand dpephos allows efficient intermolecular hydroacylation of challenging substrates (see scheme). Structural studies have established the role of the coordination of the oxygen atom, and a catalytically competent acylhydridorhodium intermediate was fully characterized. © 2006 Wiley-VCH Verlag GmbH and Co. KGaA.

Publication status:: Published

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APA Style

Moxham, G., Randell-Sly, H., Brayshaw, S., Woodward, R., Weller, A., & Willis, M. (2006). A second-generation catalyst for intermolecular hydroacylation of alkenes and alkynes using beta-S-substituted aldehydes: the role of a hemilabile P-O-P ligand. Angewandte Chemie (International Ed. in English), 45(45), 7618–7622.

MLA Style

Moxham, G, et al. “A Second-Generation Catalyst for Intermolecular Hydroacylation of Alkenes and Alkynes Using Beta-S-Substituted Aldehydes: the Role of a Hemilabile P-O-P Ligand.” Angewandte Chemie (International Ed. in English), vol. 45, no. 45, 2006, pp. 7618–22.

Chicago Style

Moxham, G, H Randell-Sly, S Brayshaw, R Woodward, A Weller, and M Willis. 2006. “A Second-Generation Catalyst for Intermolecular Hydroacylation of Alkenes and Alkynes Using Beta-S-Substituted Aldehydes: the Role of a Hemilabile P-O-P Ligand.” Angewandte Chemie (International Ed. in English) 45 (45): 7618–22.
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Publisher copy:: 10.1002/anie.200603133

Authors

+ Moxham, G More by this author

Role:: Author

+ Randell-Sly, H More by this author

Role:: Author

+ Brayshaw, S More by this author

Role:: Author

+ Woodward, R More by this author

Role:: Author

+ Weller, A More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

More authors...

Journal:: Angewandte Chemie (International ed. in English) More from this journal
Volume:: 45
Issue:: 45
Pages:: 7618-7622
Publication date:: 2006-11-01
DOI:: 10.1002/anie.200603133
EISSN:: 1521-3773
ISSN:: 1433-7851

Language:: English
Keywords:: Alkenes

Hot Temperature

Acylation

Ligands

Alkynes

Catalysis

Molecular Structure

Sulfur

Hydroxylation

Rhodium

Aldehydes
Pubs id:: pubs:51695
UUID:: uuid:1676effc-6feb-4700-98f3-f75f138ee727
Local pid:: pubs:51695
Source identifiers:: 51695
Deposit date:: 2012-12-19
ARK identifier:: ark:/29072/ora_1676effc6feb470098f3f75f138ee727

Terms of use

Copyright date:: 2006

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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