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Direct oxidation of ascorbic acid at an edge plane pyrolytic graphite electrode: A comparison of the electroanalytical response with other carbon electrodes

Abstract:
The direct electrochemical oxidation of ascorbic acid at an edge plane pyrolytic graphite electrode (EPPG) is investigated and compared with other common carbon-based electrodes, specifically glassy carbon, boron doped diamond and basal plane pyrolytic graphite. It is found that the EPPG electrode shows a significantly higher degree of electrochemical reversibility than the other electrode substrates giving rise to an analytically optimized limit of detection and sensitivity of 7.1 × 10-5 M and 0.065 A M-1 respectively.
Publication status:
Published

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Publisher copy:
10.1002/elan.200503259

Authors

More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author


Journal:
Electroanalysis More from this journal
Volume:
17
Issue:
17
Pages:
1529-1533
Publication date:
2005-09-01
DOI:
EISSN:
1521-4109
ISSN:
1040-0397


Language:
English
Keywords:
UUID:
uuid:16769676-da0a-4b50-a239-aec64a588621
Local pid:
pubs:39656
Source identifiers:
39656
Deposit date:
2012-12-19
ARK identifier:

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