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Rhodium phosphines partnered with the carborane monoanions [CB11H6Y6](-) (Y = H, Br). Synthesis and evaluation as alkene hydrogenation catalysts

Abstract:
The synthesis of rhodium phosphine complexes partnered with carborane monoanions was reported. These complexes were evaluated as alkene hydrogenation catalysts. It was demonstrated that changing the counterion within the domain of closo-monocarboranes can have a significant effect on the efficiency of hydrogenation by cationic rhodium phosphine catalysts.
Publication status:
Published

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Publisher copy:
10.1021/om020077r

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author


Journal:
ORGANOMETALLICS More from this journal
Volume:
21
Issue:
14
Pages:
2856-2865
Publication date:
2002-07-08
DOI:
EISSN:
1520-6041
ISSN:
0276-7333


Language:
English
Pubs id:
pubs:51715
UUID:
uuid:1671312c-a937-4b9d-9d0a-c4c1f3f7ad50
Local pid:
pubs:51715
Source identifiers:
51715
Deposit date:
2012-12-19

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