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The renaissance of dye-sensitized solar cells

Abstract:
Several recent major advances in the design of dyes and electrolytes for dye-sensitized solar cells have led to record power-conversion efficiencies. Donor-pi-acceptor dyes absorb much more strongly than commonly employed ruthenium-based dyes, thereby allowing most of the visible spectrum to be absorbed in thinner films. Light-trapping strategies are also improving photon absorption in thin films. New cobalt-based redox couples are making it possible to obtain higher open-circuit voltages, leading to a new record power-conversion efficiency of 12.3%. Solid-state hole conductor materials also have the potential to increase open-circuit voltages and are making dye-sensitized solar cells more manufacturable. Engineering the interface between the titania and the hole transport material is being used to reduce recombination and thus attain higher photocurrents and open-circuit voltages. The combination of these strategies promises to provide much more efficient and stable solar cells, paving the way for large-scale commercialization. © 2012 Macmillan Publishers Limited. All rights reserved.
Publication status:
Published

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Publisher copy:
10.1038/NPHOTON.2012.22

Authors

More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Physics
Sub department:
Condensed Matter Physics
Role:
Author


Journal:
NATURE PHOTONICS More from this journal
Volume:
6
Issue:
3
Pages:
162-169
Publication date:
2012-03-01
DOI:
EISSN:
1749-4893
ISSN:
1749-4885


Language:
English
Pubs id:
pubs:321691
UUID:
uuid:15f32dad-59c3-410b-9cce-549544a2770d
Local pid:
pubs:321691
Source identifiers:
321691
Deposit date:
2013-11-16
ARK identifier:

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