Journal article
IODIDE-ION QUENCHING OF THE PHOTOLYSIS OF 1-IODOANTHRAQUINONE ANION RADICAL - EVIDENCE FOR AN ARYL RADICAL NUCLEOPHILE REACTION
- Abstract:
- The photolysis of 1-iodoanthraquinone anion radical in acetonitrile containing tetrabutylammonium iodide(TBA+l-) is unaffected by changes in [TBA+|-] up to 0.2 mol dm-3, confirming that the previously observed iodide ion quenching results from capture of photogenerated aryl radicals by the nucleophilic iodide, a process analogous to that in nucleophilic aromatic substitution by the SRN1 mechanism.
- Publication status:
- Published
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- Publisher copy:
- 10.1039/p29920000147
Authors
- Journal:
- JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 More from this journal
- Issue:
- 2
- Pages:
- 147-148
- Publication date:
- 1992-02-01
- DOI:
- EISSN:
-
1364-5471
- ISSN:
-
0300-9580
- Language:
-
English
- UUID:
-
uuid:15bdc468-c031-4a83-ab04-6bcd3132b3a2
- Local pid:
-
pubs:43848
- Source identifiers:
-
43848
- Deposit date:
-
2012-12-19
- ARK identifier:
Terms of use
- Copyright date:
- 1992
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