Journal article

Relaxometric and luminescence behaviour of triaquahexaazamacrocyclic complexes, the gadolinium complex displaying a high relaxivity with a pronounced pH dependence

Abstract:: The relaxivity of [GdL1]3+ in aqueous solution has been studied as a function of temperature and magnetic field strength. The complex possesses a high relaxivity at pH 6 (12.8 mmol-1 s-1) that diminishes as successive water molecules are deprotonated, leading to a complex species whose relaxivity is typical of a purely outer-sphere complex. Measurements of the luminescence lifetime of a very similar complex, [YbL2]3+, in H2O and D2O were used to confirm that the complex possesses three bound waters at pH 5.5, but above pH 11 there are no bound OH groups in the putative di-oxo-bridged dimer.

Publication status:: Published

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APA Style

Hall, J., Haner, R., Aime, S., Botta, M., Faulkner, S., Parker, D., & de Sousa, A. (1998). Relaxometric and luminescence behaviour of triaquahexaazamacrocyclic complexes, the gadolinium complex displaying a high relaxivity with a pronounced pH dependence. NEW JOURNAL OF CHEMISTRY, 22(6), 627–631.

MLA Style

Hall, J., et al. “Relaxometric and Luminescence Behaviour of Triaquahexaazamacrocyclic Complexes, the Gadolinium Complex Displaying a High Relaxivity with a Pronounced PH Dependence.” NEW JOURNAL OF CHEMISTRY, vol. 22, no. 6, 1998, pp. 627–31.

Chicago Style

Hall, J, R Haner, S Aime, M Botta, S Faulkner, D Parker, and A de Sousa. 1998. “Relaxometric and Luminescence Behaviour of Triaquahexaazamacrocyclic Complexes, the Gadolinium Complex Displaying a High Relaxivity with a Pronounced PH Dependence.” NEW JOURNAL OF CHEMISTRY 22 (6): 627–31.
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Publisher copy:: 10.1039/a709264d

Authors

+ Hall, J More by this author

Role:: Author

+ Haner, R More by this author

Role:: Author

+ Aime, S More by this author

Role:: Author

+ Botta, M More by this author

Role:: Author

+ Faulkner, S More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

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Journal:: NEW JOURNAL OF CHEMISTRY More from this journal
Volume:: 22
Issue:: 6
Pages:: 627-631
Publication date:: 1998-06-01
DOI:: 10.1039/a709264d
EISSN:: 1369-9261
ISSN:: 1144-0546

Language:: English
Pubs id:: pubs:46813
UUID:: uuid:15a96701-3a8f-403b-ae7f-e6d75e977b72
Local pid:: pubs:46813
Source identifiers:: 46813
Deposit date:: 2012-12-19

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Copyright date:: 1998

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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