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RATE-CONSTANT FOR REACTION OF CH (X2-PI) WITH KETENE

Abstract:
A bimolecular rate constant for the reactive removal of CH (X 2Π) by ketene (CH2CO) has been measured under pseudo-first-order conditions using multiphoton dissociation of CH2CO at 308 nm to generate the radicals and laser induced fluorescence to detect them. A value of (2.4 ± 0.2) × 10-10 cm3 molecule-1 s-1 was obtained at room temperature (295 ± 2 K).
Publication status:
Published

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Publisher copy:
10.1039/ft9928802121

Authors

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author

Journal:
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS More from this journal
Volume:
88
Issue:
15
Pages:
2121-2123
Publication date:
1992-08-07
DOI:
EISSN:
1364-5455
ISSN:
0956-5000

Language:
English
Pubs id:
pubs:43873
UUID:
uuid:1577dfb8-b3b5-4212-b4ca-58f56b080d8b
Local pid:
pubs:43873
Source identifiers:
43873
Deposit date:
2012-12-19
ARK identifier:

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