Journal article

Intercalation of catalytically active metal complexes in phyllosilicates and their application as propene polymerisation catalysts

Abstract:: The cationic Ziegler-Natta polymerisation catalyst [Zr(η-C5H5Me(thf)]+, is intercalated in a synthetic fluorinated mica-type silicate (NaMg2.5Si4O10F2) and the modified, swelling synthetic hectorite [LaponiteRD, Na0.46Mg5.42Li0.46Si8(OH) 4O20], by ion-exchange of [Zr(η-C5H5Me(thf)]+ ions with the interlamellar cations of the layered silicates; in the presence of methylalumoxane {MAO, (MeAlO)n} these organometallic intercalation compounds are active catalysts for the polymerisation of propene giving low molecular mass atactic polypropylene with a narrow molecular mass distribution. † D. O'Hare is the Royal Society of Chemistry Sir Edward Frankland Fellow.

Publication status:: Published

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APA Style

Tudor, J., Willington, L., OHare, D., & Royan, B. (1996). Intercalation of catalytically active metal complexes in phyllosilicates and their application as propene polymerisation catalysts. CHEMICAL COMMUNICATIONS, 17, 2031–2032.

MLA Style

Tudor, J, et al. “Intercalation of Catalytically Active Metal Complexes in Phyllosilicates and Their Application as Propene Polymerisation Catalysts.” CHEMICAL COMMUNICATIONS, no. 17, 1996, pp. 2031–32.

Chicago Style

Tudor, J, L Willington, D OHare, and B Royan. 1996. “Intercalation of Catalytically Active Metal Complexes in Phyllosilicates and Their Application as Propene Polymerisation Catalysts.” CHEMICAL COMMUNICATIONS, no. 17: 2031–32.
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Publisher copy:: 10.1039/cc9960002031

Authors

+ Tudor, J More by this author

Role:: Author

+ Willington, L More by this author

Role:: Author

+ OHare, D More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

+ Royan, B More by this author

Role:: Author

Journal:: CHEMICAL COMMUNICATIONS More from this journal
Issue:: 17
Pages:: 2031-2032
Publication date:: 1996-09-07
DOI:: 10.1039/cc9960002031
EISSN:: 1364-548X
ISSN:: 1359-7345

Pubs id:: pubs:51455
UUID:: uuid:1551a43b-3ac9-4152-aec4-88ec9999f341
Local pid:: pubs:51455
Source identifiers:: 51455
Deposit date:: 2012-12-19
ARK identifier:: ark:/29072/ora_1551a43b3ac94152aec488ec9999f341

Terms of use

Copyright date:: 1996

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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