Journal article

Ferrocene-appended and bridged calixarene ligands for the electrochemical sensing of trivalent lanthanide ions

Abstract:: A novel family of ferrocene-derivatised calix[4]arene ligands possessing ester amide and acid amide co-ordination groups has been prepared. UV/VIS, electrospray mass spectrometry and electrochemical co-ordination studies reveal these ligands form thermodynamically 1:1 stable complexes with lanthanide ions. Electrochemical studies show these redox-active ligands electrochemically recognise trivalent lanthanide ions via significant anodic perturbations of the ferrocene-ferrocenium redox couple. With a ferrocene-bridged calixarene dimer containing ester, amide and phenolic co-ordination functionalities, anodic shifts as large as 200 mV are observed on addition of one equivalent of lanthanide ion. © The Royal Society of Chemistry 2000.

Publication status:: Published

Actions

Email

Email this record

Send the bibliographic details of this record to your email address.

Your Email
Please enter the email address that the record information will be sent to.

-
Your message (optional)
Please add any additional information to be included within the email.
Share
Cite

Cite this record

APA Style

Brindley, G., Fox, O., & Beer, P. (2000). Ferrocene-appended and bridged calixarene ligands for the electrochemical sensing of trivalent lanthanide ions. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 23, 4354–4359.

MLA Style

Brindley, G, et al. “Ferrocene-Appended and Bridged Calixarene Ligands for the Electrochemical Sensing of Trivalent Lanthanide Ions.” JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, no. 23, 2000, pp. 4354–59.

Chicago Style

Brindley, G, O Fox, and P Beer. 2000. “Ferrocene-Appended and Bridged Calixarene Ligands for the Electrochemical Sensing of Trivalent Lanthanide Ions.” JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, no. 23: 4354–59.
Print

Access Document

Publisher copy:: 10.1039/b007146n

Authors

+ Brindley, G More by this author

Role:: Author

+ Fox, O More by this author

Role:: Author

+ Beer, P More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

Journal:: JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS More from this journal
Issue:: 23
Pages:: 4354-4359
Publication date:: 2000-01-01
DOI:: 10.1039/b007146n
EISSN:: 1364-5447
ISSN:: 1470-479X

Language:: English
Pubs id:: pubs:37669
UUID:: uuid:15134177-8a60-4a36-bf67-4dd676335171
Local pid:: pubs:37669
Source identifiers:: 37669
Deposit date:: 2012-12-19
ARK identifier:: ark:/29072/ora_151341778a604a36bf674dd676335171

Terms of use

Copyright date:: 2000

Licence:: Terms and Conditions of Use for Oxford University Research Archive

Views and Downloads

About views and downloads

If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP