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The role of phase in molecular Rydberg wave packet dynamics

Abstract:
The dynamics of Rydberg electron wave packets in a molecular system was investigated. Peaks in the autocorrelation function of a wave packet composed predominantly of two interleaved Rydberg series were observed at a stroboscopic period, which depends on both the difference in the ionization limits of the two series, and on the quantum defects. This observation was rationalized by viewing the system as one in which two electron wave packets evolve independently until they overlap spatially.
Publication status:
Published

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Publisher copy:
10.1063/1.1589473

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Journal:
JOURNAL OF CHEMICAL PHYSICS More from this journal
Volume:
119
Issue:
6
Pages:
3085-3091
Publication date:
2003-08-08
DOI:
ISSN:
0021-9606


Language:
English
Pubs id:
pubs:172020
UUID:
uuid:15032fee-61b8-45f4-bbef-bc3aad01b07f
Local pid:
pubs:172020
Source identifiers:
172020
Deposit date:
2013-11-16
ARK identifier:

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