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Magnetism and structural chemistry of the n=2 Ruddlesden-Popper phase La3LiMnO7

Abstract:

Polycrystalline samples of the n=2 Ruddlesden-Popper phase La 3LiMnO7 have been prepared and characterized. X-ray and neutron diffraction suggest that the structure is tetragonal with a disordered distribution of Li and Mn cations over the octahedral sites, but 6Li MAS NMR shows that the Li and Mn are 1:1 ordered locally. Electron microscopy shows that the stacking of the cation-ordered, perovskite-like bilayers along the crystallographic z-axis is disordered on the distance scale sampled by ...

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Publication status:
Published

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Burley, JC More by this author
Gallon, DJ More by this author
Journal:
JOURNAL OF SOLID STATE CHEMISTRY
Volume:
177
Issue:
1
Pages:
119-125
Publication date:
2004-01-05
DOI:
ISSN:
0022-4596
URN:
uuid:14f48e2c-eff0-40b2-a750-f5024b85904f
Source identifiers:
38928
Local pid:
pubs:38928
Language:
English
Keywords:

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