Magnetic ordering in nitrides with the eta-carbide structure, (Ni,Co,Fe)2(Ga,Ge)Mo3N.
Compositions in the series Ni(2-x)Co(x)GeMo(3)N (0 < or = x < or = 2), Co(2)Ge(1-x)Ga(x)Mo(3)N (0 < x < or = 0.7), Co(2-x)Fe(x)GeMo(3)N (0 < or = x < or = 2), and Co(2-x)Fe(x)Ge(0.5)Ga(0.5)Mo(3)N (0 < or = x < or = 0.8) have been synthesized by the reductive nitridation of binary oxides and studied by appropriate combinations of magnetometry, transport measurements, neutron diffraction, and Mossbauer spectroscopy. All of these compositions adopt the cubic eta-carbide s...Expand abstract
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