Journal article

A rhodium complex with one Rh...C-C and one Rh...H-C agostic bond.

Abstract:: (Figure Presented) Hidden qualities: [Rh(PiPr3) (C 14H16)]-[BArF4] (1; see picture of the cation; P violet, Rh olive green), which was synthesized by treatment of [RhCl(nbd)-(PiPr3)] with Na[BArF4] (BAr F4 = B{C6H3-(CF3) 2}4) and norbornadiene (nbd) in fluorobenzene, contains an organic fragment derived from Binor-S as well as agostic Rh⋯CC and Rh⋯HC interactions. In solution, 1 undergoes rapid, reversible C-C activation/reductive elimination. © 2006 Wiley-VCH Verlag GmbH and Co. KGaA.

Publication status:: Published

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APA Style

Brayshaw, S., Green, J., Kociok-Köhn, G., Sceats, E., & Weller, A. (2006). A rhodium complex with one Rh...C-C and one Rh...H-C agostic bond. Angewandte Chemie (International Ed. in English), 45(3), 452–456.

MLA Style

Brayshaw, S, et al. “A Rhodium Complex with One Rh...C-C and One Rh...H-C Agostic Bond.” Angewandte Chemie (International Ed. in English), vol. 45, no. 3, 2006, pp. 452–56.

Chicago Style

Brayshaw, S, J Green, G Kociok-Köhn, E Sceats, and A Weller. 2006. “A Rhodium Complex with One Rh...C-C and One Rh...H-C Agostic Bond.” Angewandte Chemie (International Ed. in English) 45 (3): 452–56.
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Publisher copy:: 10.1002/anie.200503036

Authors

+ Brayshaw, S More by this author

Role:: Author

+ Green, J More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

+ Kociok-Köhn, G More by this author

Role:: Author

+ Sceats, E More by this author

Role:: Author

+ Weller, A More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

Journal:: Angewandte Chemie (International ed. in English) More from this journal
Volume:: 45
Issue:: 3
Pages:: 452-456
Publication date:: 2006-01-01
DOI:: 10.1002/anie.200503036
EISSN:: 1521-3773
ISSN:: 1433-7851

Language:: English
Keywords:: Models, Molecular

Organometallic Compounds

Rhodium

Carbon

Molecular Conformation

Hydrogen

Crystallography, X-Ray
Pubs id:: pubs:39829
UUID:: uuid:14e77be0-637a-42a7-ba53-38e7aa2bb7d1
Local pid:: pubs:39829
Source identifiers:: 39829
Deposit date:: 2012-12-19
ARK identifier:: ark:/29072/ora_14e77be0637a42a7ba5338e7aa2bb7d1

Terms of use

Copyright date:: 2006

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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