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Graphite impurities cause the observed 'electrocatalysis' seen at C-60 modified glassy carbon electrodes in respect of the oxidation of L-cysteine

Abstract:
The recently reported claims of electrocatalysis using C60 film modified glassy carbon electrodes [W.T. Tan, A.M. Bond, S.W. Ngooi, E.B. Lim, J.K. Goh, Anal. Chim. Acta 491 (2003) 181] for the oxidation of l-cysteine are questioned. We show that C60 itself is not electrocatalytic at the potentials concerned but rather it is likely that graphite impurities in the C60 material used by Tan et al. that provide their observed 'electrocatalysis'. © 2006 Elsevier B.V. All rights reserved.
Publication status:
Published

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Publisher copy:
10.1016/j.aca.2006.02.066

Authors

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author


Journal:
ANALYTICA CHIMICA ACTA More from this journal
Volume:
566
Issue:
1
Pages:
1-4
Publication date:
2006-04-27
DOI:
ISSN:
0003-2670


Language:
English
Keywords:
Pubs id:
pubs:39913
UUID:
uuid:14e6216b-bfcb-495d-af3e-bb7a5b140fe8
Local pid:
pubs:39913
Source identifiers:
39913
Deposit date:
2012-12-19
ARK identifier:

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