- Abstract:
- The statistical model of atom-diatom insertion reactions was combined with CC capture theory. The resultant methodology was employed to calculate differential cross sections for the reactions of C(1D), N(2D), O(1D) and S(1D) with H2. A comparison of the resulting initial state-selected differential cross sections with the exact quantum reactive scattering calculations of Honvaultand Launay showed that all four reactions behave essentially statistically on their ground adiabatic potential energy surfaces.
- Publication status:
- Published
- Publisher copy:
- 10.1063/1.1628218
-
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- Journal:
- JOURNAL OF CHEMICAL PHYSICS
- Volume:
- 119
- Issue:
- 24
- Pages:
- 12895-12907
- Publication date:
- 2003-12-22
- DOI:
- ISSN:
-
0021-9606
- URN:
-
uuid:14baed55-c6a7-4872-b47a-0387a46f641e
- Source identifiers:
-
38862
- Local pid:
- pubs:38862
- Language:
- English
- Copyright date:
- 2003
Journal article
A rigorous test of the statistical model for atom-diatom insertion reactions
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