Journal article icon

Journal article

A rigorous test of the statistical model for atom-diatom insertion reactions

Abstract:
The statistical model of atom-diatom insertion reactions was combined with CC capture theory. The resultant methodology was employed to calculate differential cross sections for the reactions of C(1D), N(2D), O(1D) and S(1D) with H2. A comparison of the resulting initial state-selected differential cross sections with the exact quantum reactive scattering calculations of Honvaultand Launay showed that all four reactions behave essentially statistically on their ground adiabatic potential energy surfaces.
Publication status:
Published

Actions


Access Document


Publisher copy:
10.1063/1.1628218

Authors


Rackham, EJ More by this author
Gonzalez-Lezana, T More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Journal:
JOURNAL OF CHEMICAL PHYSICS
Volume:
119
Issue:
24
Pages:
12895-12907
Publication date:
2003-12-22
DOI:
ISSN:
0021-9606
URN:
uuid:14baed55-c6a7-4872-b47a-0387a46f641e
Source identifiers:
38862
Local pid:
pubs:38862
Language:
English

Terms of use


Metrics



If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP