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Negative area compressibility in silver(I) tricyanomethanide.

Abstract:
The molecular framework Ag(tcm) (tcm(-) = tricyanomethanide) expands continuously in two orthogonal directions under hydrostatic compression. The first of its kind, this negative area compressibility behaviour arises from the flattening of honeycomb-like layers during rapid pressure-driven collapse of the interlayer separation.
Publication status:
Published

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Publisher copy:
10.1039/c3cc47032f

Authors


Hodgson, SA More by this author
Adamson, J More by this author
Cliffe, MJ More by this author
Cairns, AB More by this author
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Publisher:
Royal Society of Chemistry
Journal:
Chemical communications (Cambridge, England)
Volume:
50
Issue:
40
Pages:
5264-5266
Publication date:
2014-05-05
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
URN:
uuid:14abd3c5-f476-4431-8461-ccbf649e9cd2
Source identifiers:
444037
Local pid:
pubs:444037
Language:
English

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