- Abstract:
- The molecular framework Ag(tcm) (tcm(-) = tricyanomethanide) expands continuously in two orthogonal directions under hydrostatic compression. The first of its kind, this negative area compressibility behaviour arises from the flattening of honeycomb-like layers during rapid pressure-driven collapse of the interlayer separation.
- Publication status:
- Published
- Publisher copy:
- 10.1039/c3cc47032f
-
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- Publisher:
- Royal Society of Chemistry
- Journal:
- Chemical communications (Cambridge, England)
- Volume:
- 50
- Issue:
- 40
- Pages:
- 5264-5266
- Publication date:
- 2014-05-05
- DOI:
- EISSN:
-
1364-548X
- ISSN:
-
1359-7345
- URN:
-
uuid:14abd3c5-f476-4431-8461-ccbf649e9cd2
- Source identifiers:
-
444037
- Local pid:
- pubs:444037
- Language:
- English
- Copyright date:
- 2014
Journal article
Negative area compressibility in silver(I) tricyanomethanide.
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