Journal article
Syntheses and Structural Diversity of Group 2 and Group 12 Tris(pyrazolyl)methane and Zwitterionic Tris(pyrazolyl)methanide Compounds
- Abstract:
-
Reaction of HC(Me2pz)3 with Mg(N(SiMe 3)2}2 gave the zwitterionic amide complex Mg{C(Me2pz)3}{N(SiMe3)2} (13), containing a "free" pyramidal carbanion and a cationic {Mg-N(SiMe 3)2}+ moiety. Reaction of the less bulky amide Mg{N(SiHMe2)2}2 with RC(Me2pz) 3 (R = H or D) gave the four-coordinate adducts Mg{k 2N-RC(Me2pz)3}(N(SiHMe2) 2}2 (R = H (15) or D (15-d)). A similar complex, Mg{k 2N-HC(Me2pz)3}{N(SiMe3)2}2 (14), was observed by NMR spectroscopy at low temperatures. On warming, 15, 15-d, a...
Expand abstract
- Publication status:
- Published
Actions
Access Document
- Publisher copy:
- 10.1021/om901013b
Why is the content I wish to access not available via ORA?
Bibliographic data (the information relating to research outputs) and full-text items (e.g. articles, theses, reports, etc.) arrive in ORA from several different sources. Unfortunately we are not able to make available the full-text for every research output.
Please contact the ORA team (
) if you have queries regarding unavailable content OR if you are aware of a full-text copy we can make available.
) if you have queries regarding unavailable content OR if you are aware of a full-text copy we can make available.
Content may be unavailable for the following four reasons
-
Version unsuitable
-
We have not obtained a suitable full-text for a given research output. See this page for more information.
-
Recently completed
-
Sometimes content is held in ORA but is unavailable for a fixed period of time to comply with the policies and wishes of rights holders.
-
Permissions
-
All content made available in ORA should comply with relevant rights, such as copyright. See this page for more information.
-
Clearance
-
Some thesis volumes scanned as part of the digitisation scheme funded by Dr Leonard Polonsky are currently unavailable due to sensitive material or uncleared third-party copyright content. We are attempting to contact authors whose theses are affected.
Alternative access to the full-text
You may be able to access the full-text directly from the publisher's website using the 'Publisher Copy' link in the 'Links & Downloads' box from a research output's ORA record page. This method may require an institutional or individual subscription to the journal/resource.
Authors
Bibliographic Details
- Journal:
- ORGANOMETALLICS
- Volume:
- 29
- Issue:
- 5
- Pages:
- 1174-1190
- Publication date:
- 2010-03-08
- DOI:
- EISSN:
-
1520-6041
- ISSN:
-
0276-7333
- Source identifiers:
-
51244
Item Description
- Language:
- English
- Pubs id:
-
pubs:51244
- UUID:
-
uuid:14957f02-e31c-4549-bc5e-907e41a1f32e
- Local pid:
- pubs:51244
- Deposit date:
- 2012-12-19
Terms of use
- Copyright date:
- 2010
If you are the owner of this record, you can report an update to it here: Report update to this record