Journal article
Syntheses and Structural Diversity of Group 2 and Group 12 Tris(pyrazolyl)methane and Zwitterionic Tris(pyrazolyl)methanide Compounds
- Abstract:
-
Reaction of HC(Me2pz)3 with Mg(N(SiMe 3)2}2 gave the zwitterionic amide complex Mg{C(Me2pz)3}{N(SiMe3)2} (13), containing a "free" pyramidal carbanion and a cationic {Mg-N(SiMe 3)2}+ moiety. Reaction of the less bulky amide Mg{N(SiHMe2)2}2 with RC(Me2pz) 3 (R = H or D) gave the four-coordinate adducts Mg{k 2N-RC(Me2pz)3}(N(SiHMe2) 2}2 (R = H (15) or D (15-d)). A similar complex, Mg{k 2N-HC(Me2pz)3}{N(SiMe3)2}2 (14), was observed by NMR spectroscopy at low temperatures. On warming, 15, 15-d, a...
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- Publication status:
- Published
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- Publisher copy:
- 10.1021/om901013b
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Bibliographic Details
- Journal:
- ORGANOMETALLICS
- Volume:
- 29
- Issue:
- 5
- Pages:
- 1174-1190
- Publication date:
- 2010-03-08
- DOI:
- EISSN:
-
1520-6041
- ISSN:
-
0276-7333
- URN:
-
uuid:14957f02-e31c-4549-bc5e-907e41a1f32e
- Source identifiers:
-
51244
- Local pid:
- pubs:51244
Item Description
- Language:
- English
Terms of use
- Copyright date:
- 2010
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