Journal article

Novel alkylation, lactonisation and cascade coupling processes mediated by lead tetracarboxylates: the importance of ligands

Abstract:: The reactions of lead(IV) tetracarboxylates with carboxylic acids containing unsaturated side chains is reported. At elevated temperature in toluene, facile decarboxylation or lactonisation processes are observed, depending on the length of the carboxylate side chain and in some cases further cascade coupling processes with added nucleophiles are possible. The efficiency of these processes depends on the structure of the carboxylate ligand and the mechanistic implications of these results are briefly discussed. © 2002 Elsevier Science Ltd. All rights reserved.

Publication status:: Published

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APA Style

Moloney, M., Nettleton, E., & Smithies, K. (2002). Novel alkylation, lactonisation and cascade coupling processes mediated by lead tetracarboxylates: the importance of ligands. TETRAHEDRON LETTERS, 43(5), 907–909.

MLA Style

Moloney, M., et al. “Novel Alkylation, Lactonisation and Cascade Coupling Processes Mediated by Lead Tetracarboxylates: the Importance of Ligands.” TETRAHEDRON LETTERS, vol. 43, no. 5, 2002, pp. 907–09.

Chicago Style

Moloney, M, E Nettleton, and K Smithies. 2002. “Novel Alkylation, Lactonisation and Cascade Coupling Processes Mediated by Lead Tetracarboxylates: the Importance of Ligands.” TETRAHEDRON LETTERS 43 (5): 907–9.
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Publisher copy:: 10.1016/S0040-4039(01)02288-2

Authors

+ Moloney, M More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Organic Chemistry
Role:: Author

+ Nettleton, E More by this author

Role:: Author

+ Smithies, K More by this author

Role:: Author

Journal:: TETRAHEDRON LETTERS More from this journal
Volume:: 43
Issue:: 5
Pages:: 907-909
Publication date:: 2002-01-28
DOI:: 10.1016/S0040-4039(01)02288-2
ISSN:: 0040-4039

Language:: English
Pubs id:: pubs:38104
UUID:: uuid:148ea4b8-0e74-4818-8431-5dcd66b6263a
Local pid:: pubs:38104
Source identifiers:: 38104
Deposit date:: 2012-12-19

Terms of use

Copyright date:: 2002

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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