Journal article

Gold-Catalyzed Diastereoselective Synthesis of alpha-Fluoroenones from Propargyl Acetates

Abstract:: A diastereoselective preparation of -fluoroenones from propargyl acetates has been developed proceeding via a gold-catalyzed rearrangement-fluorination cascade. Control reactions are consistent with a mechanism involving a gold-mediated 3,3-sigmatropic shift followed by a direct, nongold-catalyzed electrophilic fluorination of the allenyl acetate intermediate. © 2010 Georg Thieme Verlag Stuttgart · New York.

Publication status:: Published

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APA Style

Hopkinson, M., Giuffredi, G., Gee, A., & Gouverneur, V. (2010). Gold-Catalyzed Diastereoselective Synthesis of alpha-Fluoroenones from Propargyl Acetates. SYNLETT, 2010(18), 2737–2742.

MLA Style

Hopkinson, M, et al. “Gold-Catalyzed Diastereoselective Synthesis of Alpha-Fluoroenones from Propargyl Acetates.” SYNLETT, vol. 2010, no. 18, 2010, pp. 2737–42.

Chicago Style

Hopkinson, M, G Giuffredi, A Gee, and V Gouverneur. 2010. “Gold-Catalyzed Diastereoselective Synthesis of Alpha-Fluoroenones from Propargyl Acetates.” SYNLETT 2010 (18): 2737–42.
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Publisher copy:: 10.1055/s-0030-1258992

Authors

+ Hopkinson, M More by this author

Role:: Author

+ Giuffredi, G More by this author

Role:: Author

+ Gee, A More by this author

Role:: Author

+ Gouverneur, V More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Organic Chemistry
Role:: Author

Journal:: SYNLETT More from this journal
Volume:: 2010
Issue:: 18
Pages:: 2737-2742
Publication date:: 2010-11-01
DOI:: 10.1055/s-0030-1258992
EISSN:: 1437-2096
ISSN:: 0936-5214

Language:: English
Keywords:: fluorine

catalysis

diastereoselectivity

rearrangement

gold
Pubs id:: pubs:97307
UUID:: uuid:1468b5b0-927d-4214-b402-cba5756705f1
Local pid:: pubs:97307
Source identifiers:: 97307
Deposit date:: 2012-12-19
ARK identifier:: ark:/29072/ora_1468b5b0927d4214b402cba5756705f1

Terms of use

Copyright date:: 2010

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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