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(-)-(S)-Nakinadine B: first asymmetric synthesis.

Abstract:
(-)-(S)-Nakinadine B has been synthesized for the first time (in 9 steps and 17% overall yield from commercially available atropic acid) using the conjugate addition of lithium dibenzyl-amide to an N-α-phenylacryloyl SuperQuat derivative with in situ diastereoselective enolate protonation as the key step.
Publication status:
Published

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Publisher copy:
10.1039/c2cc34808j

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
Journal:
Chemical Communications
Volume:
48
Issue:
74
Pages:
9236-9238
Publication date:
2012-09-01
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
Source identifiers:
345610
Language:
English
Keywords:
Pubs id:
pubs:345610
UUID:
uuid:1457065f-8ad1-4389-8a5d-6d4f9a98d466
Local pid:
pubs:345610
Deposit date:
2012-12-19

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