Journal article

Quantitative Voltammetry in Weakly Supported Media: Effects of the Applied Overpotential and Supporting Electrolyte Concentration on the One Electron Oxidation of Ferrocene in Acetonitrile

Abstract:: Chronoamperometry is reported on the one electron oxidation of 3 mM ferrocene in acetonitrile using a 300 (± 5 μm radius gold hemisphere electrode. Varying concentrations of supporting electrolyte (tetra- nbutylammonium perchlorate) are used ranging from the fully supported (100 mM) to the almost completely unsupported (0.1 mM). The response is simulated using the Nernst-Plank-Poisson system of equations and excellent agreement between theory and experiment noted, so vindicating a recent theory (J. Phys. Chem. C, 2008, 112, 13716) for voltammetry in weakly supported media. © 2009 American Chemical Society.

Publication status:: Published

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APA Style

Limon-Petersen, J., Streeter, I., Rees, N., & Compton, R. (2009). Quantitative Voltammetry in Weakly Supported Media: Effects of the Applied Overpotential and Supporting Electrolyte Concentration on the One Electron Oxidation of Ferrocene in Acetonitrile. JOURNAL OF PHYSICAL CHEMISTRY C, 113(1), 333–337.

MLA Style

Limon-Petersen, J, et al. “Quantitative Voltammetry in Weakly Supported Media: Effects of the Applied Overpotential and Supporting Electrolyte Concentration on the One Electron Oxidation of Ferrocene in Acetonitrile.” JOURNAL OF PHYSICAL CHEMISTRY C, vol. 113, no. 1, 2009, pp. 333–37.

Chicago Style

Limon-Petersen, J, I Streeter, N Rees, and R Compton. 2009. “Quantitative Voltammetry in Weakly Supported Media: Effects of the Applied Overpotential and Supporting Electrolyte Concentration on the One Electron Oxidation of Ferrocene in Acetonitrile.” JOURNAL OF PHYSICAL CHEMISTRY C 113 (1): 333–37.
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Publisher copy:: 10.1021/jp809302m

Authors

+ Limon-Petersen, J More by this author

Role:: Author

+ Streeter, I More by this author

Role:: Author

+ Rees, N More by this author

Role:: Author

+ Compton, R More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Physical & Theoretical Chem
Role:: Author

Journal:: JOURNAL OF PHYSICAL CHEMISTRY C More from this journal
Volume:: 113
Issue:: 1
Pages:: 333-337
Publication date:: 2009-01-08
DOI:: 10.1021/jp809302m
EISSN:: 1932-7455
ISSN:: 1932-7447

Language:: English
UUID:: uuid:143cc5d8-e336-4a89-94b6-13ca37ead1d1
Local pid:: pubs:41007
Source identifiers:: 41007
Deposit date:: 2012-12-19
ARK identifier:: ark:/29072/ora_143cc5d8e3364a8994b613ca37ead1d1

Terms of use

Copyright date:: 2009

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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