- Abstract:
-
We report an experimental comparative evaluation of the Butler-Volmer (BV), symmetric and asymmetric Marcus-Hush (MH) kinetic formalisms. Numerical simulations using these kinetic models are employed to fit experimental cyclic voltammetry of the one-electron oxidation of tetraphenylethylene in dichloromethane under conditions of full electrolyte support at a platinum microdisk electrode. When compared with the BV formalism, the symmetric MH model is seen to give rise to an inferior quality of...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1016/j.jelechem.2012.05.015
-
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- Journal:
- JOURNAL OF ELECTROANALYTICAL CHEMISTRY
- Volume:
- 677
- Pages:
- 120-126
- Publication date:
- 2012-07-15
- DOI:
- ISSN:
-
1572-6657
- URN:
-
uuid:1438e179-5ad7-4365-9a8f-44a6c289ffcd
- Source identifiers:
-
342869
- Local pid:
- pubs:342869
- Language:
- English
- Keywords:
- Copyright date:
- 2012
Journal article
Comparative evaluation of the symmetric and asymmetric Marcus-Hush formalisms of electrode kinetics - The one-electron oxidation of tetraphenylethylene in dichloromethane on platinum microdisk electrodes
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