- Abstract:
-
This review describes how the joint experimental and computational study of a series of niobium(tris(pyrazolyl))(chloride)(alkyne)(alkyl) complexes has unearthed a very rich chemistry involving a variety of agostic interactions between the alkyl chain and the niobium centre. α and β C{single bond}H agostic, as well as α C{single bond}C agostic coordination, have been observed, in some cases in dynamic equilibrium within the same complex. The application of experimental and computational (DFT ...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1016/j.ccr.2008.07.016
-
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- Journal:
- COORDINATION CHEMISTRY REVIEWS
- Volume:
- 253
- Issue:
- 5-6
- Pages:
- 635-646
- Publication date:
- 2009-03-05
- DOI:
- ISSN:
-
0010-8545
- URN:
-
uuid:13f9698f-64c8-49d6-b8cc-0d303a48449a
- Source identifiers:
-
50489
- Local pid:
- pubs:50489
- Language:
- English
- Keywords:
- Copyright date:
- 2009
Journal article
Agostic interactions in alkyl derivatives of sterically hindered tris(pyrazolyl)borate complexes of niobium
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