- Abstract:
- Inner virtue: The reaction of [Mo(0)(GaCp*)(6)] with ZnMe(2) yields the novel multinuclear zinc system [MoZn(12)Me(9)Cp*(3)] which geometrically resembles a classical Wade-Mingos cluster (with an interstitial molybdenum atom, see picture). In reality, its electronic structure features little direct Zn-Zn bonding, relying instead on Mo-Zn three-center, two-electron bonds spanning the body diagonals of the approximately icosahedral framework.
- Publication status:
- Published
- Publisher copy:
- 10.1002/anie.200900491
-
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- Journal:
- Angewandte Chemie (International ed. in English)
- Volume:
- 48
- Issue:
- 23
- Pages:
- 4109-4111
- Publication date:
- 2009-01-01
- DOI:
- EISSN:
-
1521-3773
- ISSN:
-
1433-7851
- URN:
-
uuid:13e6a931-8bf4-49cd-8e32-31f62af3f861
- Source identifiers:
-
41184
- Local pid:
- pubs:41184
- Language:
- English
- Keywords:
- Copyright date:
- 2009
Journal article
Bridging the gap between coordination and cluster compounds: unusual bonding modes for zinc.
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