MULTICHANNEL QUANTUM-DEFECT THEORY SIMULATION OF THE ZERO-KINETIC-ENERGY PHOTOELECTRON-SPECTRUM OF H-2

Journal article

The multichannel quantum defect theory (MQDT) is applied to the simulation of the v+=2 band of the zero-kinetic-energy (ZEKE) photoelectron spectrum of molecular hydrogen and also to the photoionization spectrum involving autoionizing Rydberg states in the region between the v+=1 and v+=2 thresholds. The results of the calculations are compared with previously reported experimental results [J. Chem. Phys. 96, 4149 (1992)]. The calculations are in very good agreement with experiment and provide quantitative confirmation of the previously proposed mechanisms for intensity perturbation. © 1994 American Institute of Physics.

Authors: Softley, T; Hudson, A

• Publication status: Published
• Journal: JOURNAL OF CHEMICAL PHYSICS
• Volume: 101
• Issue: 2
• Pages: 923-928
• Publication date: 1994-07-15
• DOI: 10.1063/1.467746
• ISSN: 0021-9606
• Language: English