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The simplest amino-borane H2 B=NH2 trapped on a rhodium dimer: pre-catalysts for amine-borane dehydropolymerization

Abstract:

The μ-aminoborane complexes [Rh2(LR)2(μ–H)(μ–H2B=NHR')][BArF4] (LR = R2P(CH2)3PR2; R = Ph, iPr; R' = H, Me) form by addition of H3B·NMeR'H to [Rh(LPh)(η6–C6H5F)][BArF4]. DFT calculations demonstrate that the aminoborane interacts with the Rh centers through strong Rh–H and Rh–B interactions. Mechan...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1002/anie.201600898

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
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Funding agency for:
Kumar, A
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Funding agency for:
Weller, A
Grant:
EP/M024210/1
Rhodes Trust More from this funder
Publisher:
Wiley Publisher's website
Journal:
Angewandte Chemie International Edition Journal website
Volume:
55
Issue:
23
Pages:
6651–6656
Publication date:
2016-01-01
Acceptance date:
2016-03-23
DOI:
ISSN:
1521-3757
Source identifiers:
611457
Keywords:
Pubs id:
pubs:611457
UUID:
uuid:12eacba6-6f05-40b2-b3ce-0d618c2d3fbe
Local pid:
pubs:611457
Deposit date:
2016-03-23

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