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A comparative study of diaryl carbene insertion reactions at polymer surfaces

Abstract:

A detailed investigation of the reactions of diaryldiazo compounds for the surface modification of several polymers has been conducted. This has revealed that the rate of reaction of diaryldiazo compounds is influenced by their substituents, that the reaction is exothermic, and that the polymer itself exerts an influence on the surface modification. The results are consistent with the formation and insertion of a carbene intermediate at the polymer surface. It was further shown that such surf...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1016/j.apsusc.2018.09.182

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Institution:
University of Oxford
Department:
Chemistry
Role:
Author
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Engineering and Physical Sciences Research Council More from this funder
Publisher:
Elsevier Publisher's website
Journal:
Applied Surface Science Journal website
Volume:
465
Pages:
754-762
Publication date:
2018-09-27
Acceptance date:
2018-09-22
DOI:
ISSN:
0169-4332
Source identifiers:
926719
Language:
English
Pubs id:
pubs:926719
UUID:
uuid:129f460a-7fa0-407d-9e5d-85342dd66d18
Local pid:
pubs:926719
Deposit date:
2018-10-15

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