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Structural-magnetic correlations on the first dinuclear spin crossover d(4) system

Abstract:
The triple decker dinuclear Cr(ii) salt [(η5-C 5Me5)Cr(μ2:η5-P 5)Cr(η5-C5Me5)]+ (SbF6)- has been structurally characterised by multiple temperature X-ray diffraction experiments from 290 K to 12 K. This material shows changes in its structural features which correlate with its magnetic response, including a structural transition with a change of symmetry from the orthorhombic space group Fddd to the monoclinic I2/a at ∼160 K and an abrupt rearrangement of electron density at ∼23 K This journal is © The Royal Society of Chemistry.
Publication status:
Published

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Publisher copy:
10.1039/b612121g

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Journal:
JOURNAL OF MATERIALS CHEMISTRY
Volume:
17
Issue:
5
Pages:
485-492
Publication date:
2007-01-01
DOI:
EISSN:
1364-5501
ISSN:
0959-9428
URN:
uuid:128ebc66-2f10-4e67-bf18-1bf615a4952f
Source identifiers:
51283
Local pid:
pubs:51283
Language:
English

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