Journal article

Structural-magnetic correlations on the first dinuclear spin crossover d(4) system

Abstract:: The triple decker dinuclear Cr(ii) salt [(η5-C 5Me5)Cr(μ2:η5-P 5)Cr(η5-C5Me5)]+ (SbF6)- has been structurally characterised by multiple temperature X-ray diffraction experiments from 290 K to 12 K. This material shows changes in its structural features which correlate with its magnetic response, including a structural transition with a change of symmetry from the orthorhombic space group Fddd to the monoclinic I2/a at ∼160 K and an abrupt rearrangement of electron density at ∼23 K This journal is © The Royal Society of Chemistry.

Publication status:: Published

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APA Style

Goeta, A., Howard, J., Hughes, A., O'Hare, D., & Copley, R. (2007). Structural-magnetic correlations on the first dinuclear spin crossover d(4) system. JOURNAL OF MATERIALS CHEMISTRY, 17(5), 485–492.

MLA Style

Goeta, A., et al. “Structural-Magnetic Correlations on the First Dinuclear Spin Crossover d(4) System.” JOURNAL OF MATERIALS CHEMISTRY, vol. 17, no. 5, 2007, pp. 485–92.

Chicago Style

Goeta, A, J Howard, A Hughes, D O'Hare, and R Copley. 2007. “Structural-Magnetic Correlations on the First Dinuclear Spin Crossover d(4) System.” JOURNAL OF MATERIALS CHEMISTRY 17 (5): 485–92.
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Publisher copy:: 10.1039/b612121g

Authors

+ Goeta, A More by this author

Role:: Author

+ Howard, J More by this author

Role:: Author

+ Hughes, A More by this author

Role:: Author

+ O'Hare, D More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

+ Copley, R More by this author

Role:: Author

Journal:: JOURNAL OF MATERIALS CHEMISTRY More from this journal
Volume:: 17
Issue:: 5
Pages:: 485-492
Publication date:: 2007-01-01
DOI:: 10.1039/b612121g
EISSN:: 1364-5501
ISSN:: 0959-9428

Language:: English
Pubs id:: pubs:51283
UUID:: uuid:128ebc66-2f10-4e67-bf18-1bf615a4952f
Local pid:: pubs:51283
Source identifiers:: 51283
Deposit date:: 2012-12-19

Terms of use

Copyright date:: 2007

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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