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Bulk-mediated surface diffusion along a cylinder: Propagators and crossovers

Abstract:
We consider the effective motion along a cylinder of a particle that freely diffuses in the bulk and intermittently binds to the cylinder. From an exact approach we derive the different regimes of the effective motion along the cylinder characterized by physical rates for binding/unbinding and the bulk diffusivity. We obtain a transient regime of superdiffusion and, interestingly, a saturation regime characteristic for the cylindrical geometry. This saturation in a finite system is not terminal but eventually turns over to normal diffusion along the cylinder. The first passage behavior of particles to the cylinder surface is derived. Consequences for actual systems are discussed. © 2009 The American Physical Society.

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Publisher copy:
10.1103/PhysRevE.79.040105

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Journal:
Physical Review E - Statistical, Nonlinear, and Soft Matter Physics More from this journal
Volume:
79
Issue:
4
Publication date:
2009-04-01
DOI:
EISSN:
1550-2376
ISSN:
1539-3755


Language:
English
Pubs id:
pubs:394739
UUID:
uuid:128801d0-ae6d-47f8-af03-c820ce579525
Local pid:
pubs:394739
Source identifiers:
394739
Deposit date:
2013-11-16
ARK identifier:

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