Journal article

Cationic terminal borylene complexes: a synthetic and mechanistic investigation of M=B metathesis chemistry.

Abstract:: (Chemical Equation Presented) Halide abstraction chemistry has been exploited to generate the cationic terminal borylene complex 1, which reacts with Ph3P=S or Ph3As=O to form 3 and 4. In the case of the corresponding reaction with Ph3P=O, the intermediate 2 can be isolated, which provides evidence for a two-step addition/substitution mechanism for the overall metathesis reaction. © 2005 Wiley-VCH Verlag GmbH and Co. KGaA.

Publication status:: Published

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APA Style

Kays, D., Day, J., Ooi, L., & Aldridge, S. (2005). Cationic terminal borylene complexes: a synthetic and mechanistic investigation of M=B metathesis chemistry. Angewandte Chemie (International Ed. in English), 44(45), 7457–7460.

MLA Style

Kays, D, et al. “Cationic Terminal Borylene Complexes: a Synthetic and Mechanistic Investigation of M=B Metathesis Chemistry.” Angewandte Chemie (International Ed. in English), vol. 44, no. 45, 2005, pp. 7457–60.

Chicago Style

Kays, D, J Day, L Ooi, and S Aldridge. 2005. “Cationic Terminal Borylene Complexes: a Synthetic and Mechanistic Investigation of M=B Metathesis Chemistry.” Angewandte Chemie (International Ed. in English) 44 (45): 7457–60.
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Publisher copy:: 10.1002/anie.200502343

Authors

+ Kays, D More by this author

Role:: Author

+ Day, J More by this author

Role:: Author

+ Ooi, L More by this author

Role:: Author

+ Aldridge, S More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

Journal:: Angewandte Chemie (International ed. in English) More from this journal
Volume:: 44
Issue:: 45
Pages:: 7457-7460
Publication date:: 2005-12-01
DOI:: 10.1002/anie.200502343
EISSN:: 1521-3773
ISSN:: 1433-7851

Language:: English
Keywords:: vinylidene ligands

borylenes

metathesis

halide abstraction

boron
Pubs id:: pubs:46039
UUID:: uuid:1274022a-fc9f-4ec6-82c9-475e65369e08
Local pid:: pubs:46039
Source identifiers:: 46039
Deposit date:: 2012-12-19
ARK identifier:: ark:/29072/ora_1274022afc9f4ec682c9475e65369e08

Terms of use

Copyright date:: 2005

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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