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The electrochemistry of tetraphenyl porphyrin iron(III) within immobilized droplets supported on platinum electrodes

Abstract:

For the first time, the voltammetry of an ensemble of immobilized benzonitrile microdroplets containing 5,10,15,20-tetraphenyl-21H,23H-porphine iron (III) chloride, TPPFeCl immobilized at platinum electrodes immersed in various aqueous electrolytes has been explored. The reduction of TPPFeCl was observed with the voltammetric response seen to be highly dependent on the nature of ions in the surrounding aqueous phase. Unlike voltammetry in purely homogeneous solution the nature of the aqueous ...

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Publication status:
Published

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Publisher copy:
10.1002/elan.200503460

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
ELECTROANALYSIS
Volume:
18
Issue:
7
Pages:
649-654
Publication date:
2006-04-01
DOI:
EISSN:
1521-4109
ISSN:
1040-0397
Source identifiers:
39936
Language:
English
Keywords:
UUID:
uuid:1272944e-bb3b-4895-9816-eb5f360651a6
Local pid:
pubs:39936
Deposit date:
2012-12-19

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