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The electrochemistry of tetraphenyl porphyrin iron(III) within immobilized droplets supported on platinum electrodes

Abstract:

For the first time, the voltammetry of an ensemble of immobilized benzonitrile microdroplets containing 5,10,15,20-tetraphenyl-21H,23H-porphine iron (III) chloride, TPPFeCl immobilized at platinum electrodes immersed in various aqueous electrolytes has been explored. The reduction of TPPFeCl was observed with the voltammetric response seen to be highly dependent on the nature of ions in the surrounding aqueous phase. Unlike voltammetry in purely homogeneous solution the nature of the aqueous ...

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Publication status:
Published

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Publisher copy:
10.1002/elan.200503460

Authors


Munoz, RAA More by this author
Davies, TJ More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Journal:
ELECTROANALYSIS
Volume:
18
Issue:
7
Pages:
649-654
Publication date:
2006-04-05
DOI:
EISSN:
1521-4109
ISSN:
1040-0397
URN:
uuid:1272944e-bb3b-4895-9816-eb5f360651a6
Source identifiers:
39936
Local pid:
pubs:39936

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