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Journal article

Rovibronic photoionization dynamics of ammonia isotopomers

Abstract:

PFI-ZEKE photoelectron spectra of the [image omitted] 2B1 (v2+=3) cationic vibrational state and photoionization spectra of autoionizing Rydberg series converging on the +=1 ionization threshold of the mixed isotopomers of ammonia, NH2D and ND2H, are reported for the first time. The observed rovibronic photoionization propensities and the quantum defects of the Rydberg series indicate that the photoelectron is ejected as a superposition of even (s and d) partial-wave components in agreement w...

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Publication status:
Published

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Publisher copy:
10.1080/00268970701429889

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
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Journal:
MOLECULAR PHYSICS
Volume:
105
Issue:
11-12
Pages:
1711-1722
Publication date:
2007-01-01
DOI:
EISSN:
1362-3028
ISSN:
0026-8976
Source identifiers:
40543
Language:
English
Keywords:
Pubs id:
pubs:40543
UUID:
uuid:120d32fb-d637-42bd-9369-81ad44f5c98b
Local pid:
pubs:40543
Deposit date:
2012-12-19

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