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Rovibronic photoionization dynamics of ammonia isotopomers

Abstract:

PFI-ZEKE photoelectron spectra of the [image omitted] 2B1 (v2+=3) cationic vibrational state and photoionization spectra of autoionizing Rydberg series converging on the +=1 ionization threshold of the mixed isotopomers of ammonia, NH2D and ND2H, are reported for the first time. The observed rovibronic photoionization propensities and the quantum defects of the Rydberg series indicate that the photoelectron is ejected as a superposition of even (s and d) partial-wave components in agreement w...

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Publication status:
Published

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Publisher copy:
10.1080/00268970701429889

Authors


Hollenstein, U More by this author
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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
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Journal:
MOLECULAR PHYSICS
Volume:
105
Issue:
11-12
Pages:
1711-1722
Publication date:
2007
DOI:
EISSN:
1362-3028
ISSN:
0026-8976
URN:
uuid:120d32fb-d637-42bd-9369-81ad44f5c98b
Source identifiers:
40543
Local pid:
pubs:40543

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