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HIGH-RESOLUTION INFRARED-SPECTROSCOPY OF THE CO.CO2 VANDERWAALS MOLECULE

Abstract:

We report the infrared absorption spectrum of the CO·CO2 van der Waals molecule in the region of the CO fundamental stretching vibration. By simultaneously fitting the observed spectrum with the previously observed microwave spectrum we have determined the upper-state spectroscopic constants. These are given as νo = 2148.241 44(14) cm-1, Δνo = 4.970 28(14) cm-1, A′ = 11 869.4(1.6) MHz, B′ = 1874.68(40) MHz and C′ = 1608.77(24) MHz. Using a model including electrostatic multipole and dispersio...

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Publication status:
Published

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Publisher copy:
10.1039/ft9908601943
Journal:
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS
Volume:
86
Issue:
11
Pages:
1943-1947
Publication date:
1990-06-07
DOI:
EISSN:
1364-5455
ISSN:
0956-5000
Language:
English
Pubs id:
pubs:43372
UUID:
uuid:11f45cd2-3336-4bb0-936f-2364005c6e35
Local pid:
pubs:43372
Source identifiers:
43372
Deposit date:
2012-12-19

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