Journal article

HIGH-RESOLUTION INFRARED-SPECTROSCOPY OF THE CO.CO2 VANDERWAALS MOLECULE

Abstract:: We report the infrared absorption spectrum of the CO·CO2 van der Waals molecule in the region of the CO fundamental stretching vibration. By simultaneously fitting the observed spectrum with the previously observed microwave spectrum we have determined the upper-state spectroscopic constants. These are given as νo = 2148.241 44(14) cm-1, Δνo = 4.970 28(14) cm-1, A′ = 11 869.4(1.6) MHz, B′ = 1874.68(40) MHz and C′ = 1608.77(24) MHz. Using a model including electrostatic multipole and dispersion interactions we have constructed potentials for various structures. The experimentally observed structure is found to be the more stable.

Publication status:: Published

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APA Style

Randall, R., Summersgill, J., & Howard, B. (1990). HIGH-RESOLUTION INFRARED-SPECTROSCOPY OF THE CO.CO2 VANDERWAALS MOLECULE. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 86(11), 1943–1947.

MLA Style

Randall, R, et al. “HIGH-RESOLUTION INFRARED-SPECTROSCOPY OF THE CO.CO2 VANDERWAALS MOLECULE.” JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, vol. 86, no. 11, 1990, pp. 1943–47.

Chicago Style

Randall, R, J Summersgill, and B Howard. 1990. “HIGH-RESOLUTION INFRARED-SPECTROSCOPY OF THE CO.CO2 VANDERWAALS MOLECULE.” JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS 86 (11): 1943–47.
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Publisher copy:: 10.1039/ft9908601943

Authors

+ Randall, R More by this author

Role:: Author

+ Summersgill, J More by this author

Role:: Author

+ Howard, B More by this author

Role:: Author

Journal:: JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS More from this journal
Volume:: 86
Issue:: 11
Pages:: 1943-1947
Publication date:: 1990-06-07
DOI:: 10.1039/ft9908601943
EISSN:: 1364-5455
ISSN:: 0956-5000

Language:: English
Pubs id:: pubs:43372
UUID:: uuid:11f45cd2-3336-4bb0-936f-2364005c6e35
Local pid:: pubs:43372
Source identifiers:: 43372
Deposit date:: 2012-12-19
ARK identifier:: ark:/29072/ora_11f45cd233364bb0936f2364005c6e35

Terms of use

Copyright date:: 1990

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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