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Electrochemical molecular recognition: pathways between complexation and signalling

Abstract:
This perspective examines the mechanisms by which electrochemical recognition of various charged and neutral guest species by redox-active receptor molecules takes place. Particular emphasis is given to the intramolecular signalling pathway employed in each case. These include electrostatic interactions (through space or through conjugated bonds), conformational changes in the redox centre, participation of the redox centre in complexation and guest interference to an already present communication pathway in the host.
Publication status:
Published

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Publisher copy:
10.1039/a901462d

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
Issue:
12
Pages:
1897-1909
Publication date:
1999-06-21
DOI:
EISSN:
1364-5447
ISSN:
0300-9246
Language:
English
Pubs id:
pubs:37064
UUID:
uuid:11dd9a8c-aaad-426b-817b-e0f955ff0140
Local pid:
pubs:37064
Source identifiers:
37064
Deposit date:
2012-12-19

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