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Mechanism of solid/liquid interfacial reactions. Atomic force microscopy studies of the self-passivating reaction between solid p-chloranil and aqueous phase N,N-dimethylphenylenediamine

Abstract:: The reaction between solid p-chloranil and alkaline aqueous solutions of dimethylphenylenediamine is shown to be self-passivating owing to the formation of insoluble product at the reacting interface. In situ atomic force microscopy imaging of the reaction occurring at (010) surfaces of single crystals of p-chloranil show that the nucleation of the overgrowth is progressive and that its coverage, S, follows the time (t) dependence S(t) = 1 - exp(-k3t3), where k3 is a rate constant. Measuremen...
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APA Style

Booth, J., Compton, R., & Atherton, J. (1998). Mechanism of solid/liquid interfacial reactions. Atomic force microscopy studies of the self-passivating reaction between solid p-chloranil and aqueous phase N,N-dimethylphenylenediamine. JOURNAL OF PHYSICAL CHEMISTRY B, 102(20), 3980–3985.

MLA Style

Booth, J., et al. “Mechanism of Solid/Liquid Interfacial Reactions. Atomic Force Microscopy Studies of the Self-Passivating Reaction between Solid p-Chloranil and Aqueous Phase N,N-Dimethylphenylenediamine.” JOURNAL OF PHYSICAL CHEMISTRY B, vol. 102, no. 20, 1998, pp. 3980–85.

Chicago Style

Booth, J, R Compton, and J Atherton. 1998. “Mechanism of Solid/Liquid Interfacial Reactions. Atomic Force Microscopy Studies of the Self-Passivating Reaction between Solid p-Chloranil and Aqueous Phase N,N-Dimethylphenylenediamine.” JOURNAL OF PHYSICAL CHEMISTRY B 102 (20): 3980–85.
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Publisher copy:: 10.1021/jp980895q

Authors

+ Booth, J More by this author

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Author

+ Compton, R More by this author

Institution:

University of Oxford

Division:

MPLS

Department:

Chemistry

Sub department:

Physical & Theoretical Chem

Role:

Author

+ Atherton, J More by this author

Role:

Author

Bibliographic Details

Journal:: JOURNAL OF PHYSICAL CHEMISTRY B
Volume:: 102
Issue:: 20
Pages:: 3980-3985
Publication date:: 1998-05-14
DOI:: 10.1021/jp980895q
EISSN:: 1520-5207
ISSN:: 1089-5647

Item Description

Language:: English
UUID:: uuid:11d74775-cf6c-4dd8-ac40-29971584a58d
Local pid:: pubs:36599
Source identifiers:: 36599
Deposit date:: 2012-12-19

Terms of use

Copyright date:: 1998

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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